By Martin D. Kamen (auth.), Seymour Rothchild (eds.)
Advances in Tracer method, quantity 2, files the professional ceedings of the sixth, seventh, and eighth Symposia on Advances in Tracer method. those Symposia, that are a part of a continuous sequence backed by means of the hot England Nuclear Corp. and the Packard device corporation, Inc., are dedicated to the whole isotope tracer box: guidance and research of categorized compounds, functions within the chemical, biochemical, and scientific fields, and future health physics issues linked to tracer paintings. The papers during this quantity mirror yes developments which might be famous within the tracer box: expanding reliance on biochemical tools for labeling esoteric compounds, transforming into expertise of the issues of radiation decomposition, using complex instrumentation for the research and detection of radioactive substrates, and the quickly transforming into software of tracer compounds to scientific prognosis. the 3 Symposia at which the papers have been offered have been hung on the subsequent dates: DATE place CHAIRMAN 11/16/62 big apple urban Daniel Steinberg, leader Laboratory of Ce1lular body structure and Metabolism, nationwide center Institute, Bethesda, Maryland 3/8/63 l. a. Martin Kamen college of California San Diego, California 11/8/63 Chicago Joseph L. Rabinowitz Veterans management health facility Philadelphia, Pennsylvania once more, it's the editor's excitement to recognize the aid of his colleagues in making plans and operating a few of the Symposia, in addition to the superb cooperation of the chairmen, who acquitted themselves of their appointed initiatives in a best demeanour, With humor and realizing. S. R. Boston, Mass.
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Extra info for Advances in Tracer Methodology: Volume 2 A collection of papers presented at the Sixth, Seventh, and Eight Symposia on Tracer Methodology plus other papers selected by the editor
And Durrett, L. , Anal. Chem. 5 (1963). Farley, F. F .. and Gordon, B. , 1959 Fifth World Petroleum Congress, New York, Section X, Paper 5. International Atomic Energy Agency, Symposium on the Chemical Effects of Nuclear Transformations, Vol. II, Prague, October 1960, pp. 3-145. Kirmse, W.. Angew. Chem. 73:161 (1961). Lange, N. A.. , Handbook Publishers, Sandusky, Ohio (1946). M .. , J. Am. Chem. Soc. 81:106 (1959). , Ann. Chem. 604:151 (1957). , and Werner, H .. Chem. Ber. 75:1610 (1942). D ..
Figures 3-5 represent lower conversion runs with D20 and D2• Here the difference in the observed and calculated curves is of interest. In the observed data the high d, values, the minimum followed by the maxima at d s - d,o, require that at least two mechanisms are operating. The first is similar to that found by Burwell et al. [10,11,13] involving one exchange per adsorption. This mechanism should show no minimum after d,. The second involves several exchanges per adsorption, and when superimposed on the first, should result in a minimum.
2 __+-~ B. E. Gordon and J. J. 10/0 Yield = 27% 30 - Calculated - - Observed 8 10 Ib Number of D Atoms/Molecule Fig. 3 The calculated curves were obtained by computing the mean atom %D in the hydrocarbon (from the normalized values), and computing the curves according to the above formula. These data appear as the dashed lines in the figures. ' The close parallel between calculated and observed is not surprising if all of the hydrogens are susceptible to exchange. Thus at equilibrium the curves must coincide.